Splashup
Fairly robust image editing. Features include layers, multiple image editing, and social network integration.

Google Docs & Spreadsheets
Yes another way to rid Microsoft Office from your desktop with this excellent word processing tool.  

Weebly
I built this site from scratch using a free Weebly template. Publish a functional website with little editing knowledge in minutes.
 
Tokbox
Very simple Flash based video chat.

Flickr
Cool photo management service with tons of potabilities. Turn your photos into merchandise here.

Apart from their nationality, these men all have one thing in common. Can you guess what it is?
Amongst many other things they have achieved the following:

Jean-Dominique Bauby
Wrote an book with one eye.

Philippe Petit
Danced between the Twin Towers 417 metres above the ground.

Alain Robert
Climbed 85 very large man made structures.

1. www.ted.com [Ideas]
As the title says "Ideas worth spreading". Talks from some of the best thinkers, talkers, and doers of our time.

2. www.alluc.org [Documentaries]
Missed a good doco on BBC or Discovery? Here it is. Plus tons more.
 
3. www.itunes.com [Podcasts]
Something free from Apple. Yes I said free. Terabytes of content here. Most notably BBC Radio 4.